Why HF is a strong acid in period but HI is a strong acid in group?


Strength of acid

 

In a period left to right electronegativity increases, F is most electronegative (4.0) in a same period. So HF is a strong acid, it can easily release proton. In a group top to bottom, we will consider dissociation energy. As we move from top to bottom in a group dissociation energy decreases, hence HI has least dissociation energy as a result it becomes stronger  acid as compared to HF.

 


 Period:    CH4, NH3, H2O, HF                                           Group

                                                                                             HF

                                                                                             HCl

                                                                                             HBr

                                                                                              HI


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